This book aims to overview the variety of nanographenes. Their diverse morphologies, mostly stemming from their structural defects, different approaches of synthesis, their singular chiroptical and photophysical properties and potential applications are covered in this book. Includes both top-down approach where nanographenes are obtained from graphite by fragmentation of pristine graphene by chemical methods, leading to non-homogeneous NGs (flakes) without control of their size and shape and bottom down approach is using standard synthetic chemical protocols resulting in homogeneous and…mehr
This book aims to overview the variety of nanographenes. Their diverse morphologies, mostly stemming from their structural defects, different approaches of synthesis, their singular chiroptical and photophysical properties and potential applications are covered in this book. Includes both top-down approach where nanographenes are obtained from graphite by fragmentation of pristine graphene by chemical methods, leading to non-homogeneous NGs (flakes) without control of their size and shape and bottom down approach is using standard synthetic chemical protocols resulting in homogeneous and well-defined discrete molecules with a full control on their size and shape.
Nazario Martín, PhD, is Full Professor of Organic Chemistry at the University Complutense of Madrid and Vice-Director of the Institute of Madrid for Advanced Studies in Nanoscience, Madrid, Spain. He also served as editor-in-chief for the RSC Publications Journal of Materials Chemistry A, B and C. He has published extensively on carbon nanostructures and related subjects, and his many awards and honours include the 2012 Alexander von Humboldt award. Colin P. Nuckolls, PhD, is Sheldon and Dorothea Professor of Materials Science at Columbia University, New York, USA, where he served as Department Chair from 2008-2011. He also serves as executive editor for the ACS Publications journal NanoLetters, and his wide research experience covers molecular synthesis, reaction chemistry, and many other subjects.
Inhaltsangabe
Fundamental Concepts in Nanographenes 1. Aromaticity and Antiaromaticity in Nanographenes: An Overview 2. Covalent Patterned Functionalization of Graphene 3. Nanographenes by Bottom-up Approach: The Scholl Reaction 4. Racemization barriers in chiral molecular nanographenes
Synthesis of Molecular Nanographenes 5. Synthesis of Helicenes 6. Carbon Nanobelts 7. Negatively Curved Nanographenes 8. Highly-strained Cyclophanes and other Nanographenes 9. Chiral Bilayer Nanographenes: Synthesis and Properties 10. Large p-Extended Carbon Nanorings: From Synthesis to Properties 11. Nanographenes with Multiple Zigzag Edges 12. Monkey Saddles and other Contorted Polycyclic Aromatic Compounds 13. Conjugated Nanohoops: Synthesis, Properties and Applications 14. Synthesis of Graphene Nanoribbons, Nanographenes and Fused Aromatic Networks Through the Formation of Pyrazine Rings 15. On-surface Synthesis of p-conjugated polymers 16. Merging organic chemistry with surface synthesis for the preparation of nanographenes
Properties and Applications of Molecular Nanographenes 17. Chiral Materials from Perylene Diimide Building Blocks: Twistacenes and Helicenes 18. Circularly Polarized Luminescence (CPL) in Nanographenes 19. Open-shell Nanographenes 20. Kekulé and Non-Kekulé Nanographenes: A Magnetic Perspective 21. Redox Properties of Nanographenes
Fundamental Concepts in Nanographenes 1. Aromaticity and Antiaromaticity in Nanographenes: An Overview 2. Covalent Patterned Functionalization of Graphene 3. Nanographenes by Bottom-up Approach: The Scholl Reaction 4. Racemization barriers in chiral molecular nanographenes
Synthesis of Molecular Nanographenes 5. Synthesis of Helicenes 6. Carbon Nanobelts 7. Negatively Curved Nanographenes 8. Highly-strained Cyclophanes and other Nanographenes 9. Chiral Bilayer Nanographenes: Synthesis and Properties 10. Large p-Extended Carbon Nanorings: From Synthesis to Properties 11. Nanographenes with Multiple Zigzag Edges 12. Monkey Saddles and other Contorted Polycyclic Aromatic Compounds 13. Conjugated Nanohoops: Synthesis, Properties and Applications 14. Synthesis of Graphene Nanoribbons, Nanographenes and Fused Aromatic Networks Through the Formation of Pyrazine Rings 15. On-surface Synthesis of p-conjugated polymers 16. Merging organic chemistry with surface synthesis for the preparation of nanographenes
Properties and Applications of Molecular Nanographenes 17. Chiral Materials from Perylene Diimide Building Blocks: Twistacenes and Helicenes 18. Circularly Polarized Luminescence (CPL) in Nanographenes 19. Open-shell Nanographenes 20. Kekulé and Non-Kekulé Nanographenes: A Magnetic Perspective 21. Redox Properties of Nanographenes
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