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This comprehensive and richly illustrated review of the complex solid-state chemistry of the superconducting copper oxides will be welcomed by all researchers and graduate students interested in high Tc superconductors.
This comprehensive and richly illustrated review of the complex solid-state chemistry of the superconducting copper oxides will be welcomed by all researchers and graduate students interested in high Tc superconductors.
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Inhaltsangabe
1. Introduction: Superconductivity in Oxides Before 1986.- 2. Phases of the Systems A-La-Ca-Cu-O and A-Y-Ca-Cu-O (A = Ca, Sr, Ba): Structural Aspects.- 2.1 Copper Chemistry in Oxides: Oxidation States and Coordination.- 2.2 The Ternary Systems La-Cu-O and A-Cu-O (A = Ca,Sr,Ba).- 2.3 The Pseudoternary Systems A-La-Cu-O (A = Ca,Sr,Ba).- 2.4 The Pseudoternary System Y-Ba-Cu-O.- 2.5 The Systems Ln-Sr-Cu-O (Ln ? La).- 3. Electron Transport Properties Connected with Oxygen Nonstoichiometry.- 3.1 Electron Transport Properties in Cuprates Related to the Perovskite: General Considerations.- 3.2 Oxides with the K2NiF4-Type Structure.- 3.3 Oxides with the Oxygen-Deficient Sr3Ti2O7-Type Structure.- 3.4 Oxides with the Oxygen-Deficient Perovskite Structure.- 4. Substitutions in La2CuO4-Type and YBa2Cu3O7-Type Superconductors.- 4.1 Substitution on the Rare-Earth Sites.- 4.2 Substitution on the Copper Sites.- 4.3 Substitutions on Other Sites.- 5. Bismuth, Thallium and Lead Superconducting Cuprates.- 5.1 Bismuth Alkaline-Earth Superconducting Cuprates.- 5.2 Thallium Alkaline-Earth Superconducting Cuprates.- 5.3 Lead Alkaline-Earth Superconducting Cuprates.- 5.4 Layered Cuprates Involving Double Fluorite-Type Layers.- 5.5 Structural Relationships.- 6. Extended Defects in Superconducting Oxides: High-Resolution Electron Microscopy.- 6.1 YBa2Cu3O7-Type Superconductors: Ordering in the Perovskite Framework.- 6.3 Layer Interconnections.- 6.4 Extra Spots in ED Patterns: An Amazing Variety.- 6.5 Domains and Boundaries.- 7. Irradiation Effects in the High-Tc Superconducting Oxides.- 7.1 Radiation Damage in Solids.- 7.2 Radiation Damage by Electrons and Fast Neutrons in Copper Oxide Superconductors.- 7.3 Phase Transformations Induced by Fast Heavy Ions in the High-Tc Copper Oxides.- 7.4Conclusions.- 8. Concluding Remarks.- 8.1 Low Dimensionality of the Structure.- 8.2 Mixed Valence of Copper and Hole Delocalization.- 8.3 The Model of Copper Disproportionation.- 8.4 Role of the Lone Pair Cations and of the Alkaline Earth Elements.- References.
1. Introduction: Superconductivity in Oxides Before 1986.- 2. Phases of the Systems A-La-Ca-Cu-O and A-Y-Ca-Cu-O (A = Ca, Sr, Ba): Structural Aspects.- 2.1 Copper Chemistry in Oxides: Oxidation States and Coordination.- 2.2 The Ternary Systems La-Cu-O and A-Cu-O (A = Ca,Sr,Ba).- 2.3 The Pseudoternary Systems A-La-Cu-O (A = Ca,Sr,Ba).- 2.4 The Pseudoternary System Y-Ba-Cu-O.- 2.5 The Systems Ln-Sr-Cu-O (Ln ? La).- 3. Electron Transport Properties Connected with Oxygen Nonstoichiometry.- 3.1 Electron Transport Properties in Cuprates Related to the Perovskite: General Considerations.- 3.2 Oxides with the K2NiF4-Type Structure.- 3.3 Oxides with the Oxygen-Deficient Sr3Ti2O7-Type Structure.- 3.4 Oxides with the Oxygen-Deficient Perovskite Structure.- 4. Substitutions in La2CuO4-Type and YBa2Cu3O7-Type Superconductors.- 4.1 Substitution on the Rare-Earth Sites.- 4.2 Substitution on the Copper Sites.- 4.3 Substitutions on Other Sites.- 5. Bismuth, Thallium and Lead Superconducting Cuprates.- 5.1 Bismuth Alkaline-Earth Superconducting Cuprates.- 5.2 Thallium Alkaline-Earth Superconducting Cuprates.- 5.3 Lead Alkaline-Earth Superconducting Cuprates.- 5.4 Layered Cuprates Involving Double Fluorite-Type Layers.- 5.5 Structural Relationships.- 6. Extended Defects in Superconducting Oxides: High-Resolution Electron Microscopy.- 6.1 YBa2Cu3O7-Type Superconductors: Ordering in the Perovskite Framework.- 6.3 Layer Interconnections.- 6.4 Extra Spots in ED Patterns: An Amazing Variety.- 6.5 Domains and Boundaries.- 7. Irradiation Effects in the High-Tc Superconducting Oxides.- 7.1 Radiation Damage in Solids.- 7.2 Radiation Damage by Electrons and Fast Neutrons in Copper Oxide Superconductors.- 7.3 Phase Transformations Induced by Fast Heavy Ions in the High-Tc Copper Oxides.- 7.4Conclusions.- 8. Concluding Remarks.- 8.1 Low Dimensionality of the Structure.- 8.2 Mixed Valence of Copper and Hole Delocalization.- 8.3 The Model of Copper Disproportionation.- 8.4 Role of the Lone Pair Cations and of the Alkaline Earth Elements.- References.
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