This volume documents developments in the study of catalysis relating to organic synthesis and its application in industrial processes. It surveys a wide range of homo- and heterogeneous catalysis for industrial and pharmaceutical chemicals. It covers enantioselective hydrogenation, catalyzed hydrogens and oxidation, carbonylation, hydroaminomethylation, and more.
This volume documents developments in the study of catalysis relating to organic synthesis and its application in industrial processes. It surveys a wide range of homo- and heterogeneous catalysis for industrial and pharmaceutical chemicals. It covers enantioselective hydrogenation, catalyzed hydrogens and oxidation, carbonylation, hydroaminomethylation, and more.
The Raney-nickel; selecting between batch slurry and continuous fixed bed hydrogenation; safety and economics considerations in the design of an industrial hydrogenation facility; effect of carbon activation on deposition of Pd and Pt; the flexibility of the chemical and physical properties of metalyst for the optimal performance of fixed bed reactions on activated base metal surfaces; advanced fixed-bed hydrogenation of unsaturated fatty acids; modelling of propylene oxidation on hydrophobic catalyst in a slurry and trickle bed reactor; the safe handling of activated nickel catalysts - heat induced interactions between the catalyst, ethyl acetate and water; the effect of surface area on the partial oxidation of n-butane over VPO catalysts; reactivity of B/P/O-based heterogeneous catalysts in gas-phase o-alkylation of diphenols with methanol; production of aromatics catalyzed by commercial sulfated zirconia solid acid catalysis; vapour phase synthesis of indole and its derivatives; carbons as catalysts; new coupling and isomerization reactions catalyzed by a protic superacid; alkylation of phenol with tert-butyl alcohol catalyzed by zeolite HY catalysts; lithium hydroxide modified sponge catalysts for control of primary amine selectivity in nitrile hydrogenations; reactivity and surface analysis studies on the deactivation of Raney Ni during adiponitrile hydrogenation; catalytic hydrogenation of benzonitrile over Raney nickel -influence of reaction rates and selectivities; catalytic hydrogenation of lignin aromatics using Ru-arene complexes; reaction pathways in the catalytic reductive N-methylation of polyamines; reductive alkylation of 2-methylglutaronitrile with palladium catalysts; the synthesis of amines by catalytic hydrogenation of nitro compounds; hydrogenation of cinnamaldehyde on Ru-MCM and Ru-beta catalysts; novel preparation of 5alpha-dihydriethisterone from androst-4-ene-3, 17-dione; selective epoxidation of allylic alcohols with amine-modified titania-
The Raney-nickel; selecting between batch slurry and continuous fixed bed hydrogenation; safety and economics considerations in the design of an industrial hydrogenation facility; effect of carbon activation on deposition of Pd and Pt; the flexibility of the chemical and physical properties of metalyst for the optimal performance of fixed bed reactions on activated base metal surfaces; advanced fixed-bed hydrogenation of unsaturated fatty acids; modelling of propylene oxidation on hydrophobic catalyst in a slurry and trickle bed reactor; the safe handling of activated nickel catalysts - heat induced interactions between the catalyst, ethyl acetate and water; the effect of surface area on the partial oxidation of n-butane over VPO catalysts; reactivity of B/P/O-based heterogeneous catalysts in gas-phase o-alkylation of diphenols with methanol; production of aromatics catalyzed by commercial sulfated zirconia solid acid catalysis; vapour phase synthesis of indole and its derivatives; carbons as catalysts; new coupling and isomerization reactions catalyzed by a protic superacid; alkylation of phenol with tert-butyl alcohol catalyzed by zeolite HY catalysts; lithium hydroxide modified sponge catalysts for control of primary amine selectivity in nitrile hydrogenations; reactivity and surface analysis studies on the deactivation of Raney Ni during adiponitrile hydrogenation; catalytic hydrogenation of benzonitrile over Raney nickel -influence of reaction rates and selectivities; catalytic hydrogenation of lignin aromatics using Ru-arene complexes; reaction pathways in the catalytic reductive N-methylation of polyamines; reductive alkylation of 2-methylglutaronitrile with palladium catalysts; the synthesis of amines by catalytic hydrogenation of nitro compounds; hydrogenation of cinnamaldehyde on Ru-MCM and Ru-beta catalysts; novel preparation of 5alpha-dihydriethisterone from androst-4-ene-3, 17-dione; selective epoxidation of allylic alcohols with amine-modified titania-
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