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Di- and tri-organotin(IV) carboxylates of the type R2SnL2 [R = CH3, n-C4H9, n-C8H17] and R3SnL [R = CH3, n-C4H9, C6H5, where L= oxygen donor ligand, have been synthesized and characterized by various analytical techniques such as elemental analysis, FT-IR, NMR (1H, 13C) and single crystal X-ray analysis. The synthesized complexes were screened for their catalytic activity in synthesis of biodiesel-an alternative fuel, and biological activities such as antibacterial, antifungal and cytotoxicity. The triorganotin(IV) complexes exhibited comparatively higher catalytic and biological activities…mehr

Produktbeschreibung
Di- and tri-organotin(IV) carboxylates of the type R2SnL2 [R = CH3, n-C4H9, n-C8H17] and R3SnL [R = CH3, n-C4H9, C6H5, where L= oxygen donor ligand, have been synthesized and characterized by various analytical techniques such as elemental analysis, FT-IR, NMR (1H, 13C) and single crystal X-ray analysis. The synthesized complexes were screened for their catalytic activity in synthesis of biodiesel-an alternative fuel, and biological activities such as antibacterial, antifungal and cytotoxicity. The triorganotin(IV) complexes exhibited comparatively higher catalytic and biological activities than their diorganotin(IV) analogues. DNA interactions studies of the ligands and synthesized complexes were also investigated and the results showed that both ligands and complexes interact with DNA via intercalation as well as minor groove binding.
Autorenporträt
Dr. Muhammad Tariq did his Ph.D in 2013 under the supervision of Prof. Dr. Saqib Ali, from Department of Chemistry, Quaid-i-Azam University Islamabad, Pakistan. He has 12 international publications on his credit. His field of expertise includes organometalllic chemistry and catalysis in synthesis of biodiesel.