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In first part of series of books of General Chemistry, our aim is to provide a handy books that addresses the requirement of University Chemistry courses and bring together those areas of Chemistry that traditionally have been taught apart from one another. In this part, we have cover the basic topis of Free energy, Electrolytic conductance, Crystal Structures, Hybridization, Chemistry of alkyl halides, alcohol, phenol, etc with mechanisms that support to understand the concept. I have been always grateful to Google and Anthers & Publishers whose provide online books and other writing materials.