Modern Synthesis Processes and Reactivity of Fluorinated Compounds

Progress in Fluorine Science
Herausgegeben:Groult, Henri; Leroux, Frederic; Tressaud, Alain

• Broschiertes Buch

Produktbeschreibung

Modern Synthesis Processes and Reactivity of Fluorinated Compounds focuses on the exceptional character of fluorine and fluorinated compounds. This comprehensive work explores examples taken from all classes of fluorine chemistry and illustrates the extreme reactivity of fluorinating media and the peculiar synthesis routes to fluorinated materials.

The book provides advanced and updated information on the latest synthesis routes to fluorocompounds and the involved reaction mechanisms. Special attention is given to the unique reactivity of fluorine and fluorinated media, along with the correlation of those properties to valuable applications of fluorinated compounds.

Produktdetails

• Progress in Fluorine Science
• Verlag: Elsevier / Elsevier, München
• Artikelnr. des Verlages: C2015-0-00338-0
• Englisch
• Abmessung: 36mm x 152mm x 229mm
• Gewicht: 1250g
• ISBN-13: 9780128037409
• ISBN-10: 0128037407
• Artikelnr.: 45368069

Autorenporträt

Henri Groult is Director of Research of CNRS-UPMC-ESPCI UMR 7612, University of Pierre and Marie Curie (Paris 6) in France. He has devoted his research life to fluorine chemistry, electrochemistry, and molten salt chemistry. His main research subjects are electrolytic production of fluorine gas, fluorine compounds for primary and secondary lithium batteries, and electrochemical properties of molten fluorides and chlorides. He has obtained interesting results on fluorine evolution reaction on carbon electrodes, discharge behavior of carbon-fluorine compounds, charge/discharge characteristics of metal fluorides, and electrochemical properties of molten salts. On these subjects, he published more than 100 papers and 7 books. His activity has played an important role in fluorine chemistry in France. He has served as Director of the French Network of Fluorine, Chairman of the 17th European Symposium on Fluorine Chemistry (Paris, July 2013), and Editorial board of J. Fluorine Chemistry.

Inhaltsangabe

1. The Cosmic Origin of Fluorine: An Astronomer's View on Fluorine Synthesis
2. The Fluorine Atom in Health Care and Agrochemical Applications: A Contribution to Life Science
3. Industrial Syntheses of Hydrohaloolefins and Related Products
4. Electrochemical Fluorination: A Powerful Tool for the Preparation of Organofluorine Compounds
5. Once Upon a Time Was the Langlois' Reagent: A "Sleeping Beauty
6. Toward CF₃S Group: From Trifluoromethylation of Sulfides to Direct Trifluoromethylthiolation
7. Nucleophilic Di- and Trifluoromethylation of CO and CN Bonds
8. Oxidative Trifluoromethylation and Trifluoromethylthiolation
9. Catalytic Enantioselective Fluorination
10. Development of Electrophilic Trifluoromethylating Reagents
11. New Nucleophilic Fluoroalkylations
12. Continuous Flow Selective Direct Fluorination Using Fluorine Gas
13. Synthesis of Fluorinated Nitrogen-Containing Compounds Through Superelectrophilic Activation in Superacid HF/SbF₅
14. Visible Light-Induced (Per)fluoroalkylation by Photoredox Catalysis
15. Synthesis of Side Chain Fluorinated Amino Acids and Their Effects on the Properties of Peptides and Proteins
16. Ionic Liquids and Polymers for Battery and Fuel Cells
17. Strategic Incorporation of Fluorine for Drug Discovery and Development
18. Telomerization Reaction of 3,3,3-Trifluoropropene
19. High Oxidation States in Transition Metal Fluorides
20. Photochemical Syntheses of Fluorides in Liquid Anhydrous Hydrogen Fluoride
21. Sol-Gel Synthesis of Metal Fluorides: Reactivity and Mechanisms
22. Solution-Based Synthesis of Nano-Sized TiO₂ Anatase in Fluorinating Media
23. Ionic Liquid Materials Based on Fluoroanions
24. Reactivity of Surface Fluorinated TiO₂ and TiAl Particles
25. Chemical and Electrochemical Stability of Copper in Molten KF-2HF