A succinct review of the essential concepts of organometallic chemistry, enriched throughout with examples that demonstrate how our understanding of organometallic chemistry has led to new applications in research and industry - not least in relation to catalysis.
A succinct review of the essential concepts of organometallic chemistry, enriched throughout with examples that demonstrate how our understanding of organometallic chemistry has led to new applications in research and industry - not least in relation to catalysis.Hinweis: Dieser Artikel kann nur an eine deutsche Lieferadresse ausgeliefert werden.
Manfred Bochmann is Professor of Inorganic Chemistry and Director of the Wolfson Materials and Catalysis Centre at the University of East Anglia where his research centres broadly around synthetic organometallic and coordination chemistry directed towards homogeneous catalysis. A former Head of the School of Chemistry, in 2003 he was awarded the Royal Society of Chemistry Medal for Organometallic Chemistry. Professor Bochmann is the author of two Oxford Chemistry Primers on organometallic chemistry, and is an Associate Editor of the journal Organometallics.
Inhaltsangabe
Part 1. Organometallic Compounds of Main Group Elements 1.1: General and bonding considerations 1.2: Alkali metal organometallics: lithium 1.3: Organometallic compounds of alkaline earth metals 1.4: Zinc, cadmium and mercury 1.5: Organometallic compounds of the boron group 1.6: Organometallic compounds of the carbon group Part 2. Organometallic Compounds of Transition Metals 2.1: Ligand types 2.2: Common types of organometallic complexes 2.3: Electron counting and the 16/18-electron rule 2.4: Ligand properties and metal-ligand bonding 2.5: L-type p-acceptor ligands : metal carbonyl complexes 2.6: L-type p-acceptor ligands: alkenes, dienes and alkynes 2.7: LX- and L2X-type p-acceptor ligands: allyl and enyl complexes 2.8: L2X-type p-acceptor ligands: metallocene complexes 2.9: Arene complexes 2.10: Sigma complexes 2.11: Complexes with M-C s-bonds 2.12: Alkylidene complexes 2.13: Complexes with MC triple bonds: carbynes Part 3. Homogeneous Catalysis with Organometallic Transition Metal Complexes 3.1: General considerations 3.2: Key reaction steps in homogeneous catalysis 3.3: Catalytic H-H and H-X additions 3.4: Catalytic carbonylations 3.5: Alkene oxidations 3.6: Coupling reactions 3.7: Alkene polymerizations Appendix 1 Commonly used solvents and their properties Appendix 2 Number and symmetry of infrared-active vibrations of metal carbonyl complexes Appendix 3 Answers to exercises Appendix 4 Further reading
Part 1. Organometallic Compounds of Main Group Elements 1.1: General and bonding considerations 1.2: Alkali metal organometallics: lithium 1.3: Organometallic compounds of alkaline earth metals 1.4: Zinc, cadmium and mercury 1.5: Organometallic compounds of the boron group 1.6: Organometallic compounds of the carbon group Part 2. Organometallic Compounds of Transition Metals 2.1: Ligand types 2.2: Common types of organometallic complexes 2.3: Electron counting and the 16/18-electron rule 2.4: Ligand properties and metal-ligand bonding 2.5: L-type p-acceptor ligands : metal carbonyl complexes 2.6: L-type p-acceptor ligands: alkenes, dienes and alkynes 2.7: LX- and L2X-type p-acceptor ligands: allyl and enyl complexes 2.8: L2X-type p-acceptor ligands: metallocene complexes 2.9: Arene complexes 2.10: Sigma complexes 2.11: Complexes with M-C s-bonds 2.12: Alkylidene complexes 2.13: Complexes with MC triple bonds: carbynes Part 3. Homogeneous Catalysis with Organometallic Transition Metal Complexes 3.1: General considerations 3.2: Key reaction steps in homogeneous catalysis 3.3: Catalytic H-H and H-X additions 3.4: Catalytic carbonylations 3.5: Alkene oxidations 3.6: Coupling reactions 3.7: Alkene polymerizations Appendix 1 Commonly used solvents and their properties Appendix 2 Number and symmetry of infrared-active vibrations of metal carbonyl complexes Appendix 3 Answers to exercises Appendix 4 Further reading
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