This book serves as a resource for researchers wishing to do chemistry with silver cations, an area that stands in the shadow of gold chemistry, but is quite powerful and ultimately less expensive. It contains experimental procedures that serve as a useful guide for first attempts in working with silver cations. Written by a well-respected, highly visible authority in the field, this is the first book addressing silver cation catalysis in organic chemistry, providing a much-needed resource on mechanisms, methods, advantages, and efficiencies in organometallic synthesis.
This book serves as a resource for researchers wishing to do chemistry with silver cations, an area that stands in the shadow of gold chemistry, but is quite powerful and ultimately less expensive. It contains experimental procedures that serve as a useful guide for first attempts in working with silver cations. Written by a well-respected, highly visible authority in the field, this is the first book addressing silver cation catalysis in organic chemistry, providing a much-needed resource on mechanisms, methods, advantages, and efficiencies in organometallic synthesis.
MICHAEL HARMATA holds the academic position of Norman Rabjohn Distinguished Professor of Chemistry at the University of Missouri-Columbia. He has published extensively in his field and has been chair of the Gordon Research Conference on Organic Reactions and Processes (2000) and has served as an invited speaker at many U.S. and international universities and conferences, including the International Symposium on Molecular Recognition and Inclusion, the International Congress on Heterocyclic Chemistry, and the International IUPAC Conference on Organic Synthesis. Dr. Harmata has also served on the editorial board of Mini-Reviews in Organic Chemistry and Chemtracts Organic Chemistry. He is the Editor of Elsevier's book series, Strategies and Tactics in Organic Synthesis, and editor of Springer's Organic Mechanisms.
Inhaltsangabe
Foreword. Preface. Contributors. 1 Silver Alkyls, Alkenyls, Aryls, and Alkynyls in Organic Synthesis ( Rebecca H. Pouwer and Craig M. Williams). 2 Cycloaddition Reactions (Alex M. Szpilman and Erick M. Carreira). 3 Sigmatropic Rearrangements and Related Processes Promoted by Silver ( Jean-Marc Weibel, Aurélien Blanc, and Patrick Pale). 4 Silver(I)-Mediated Electrocyclic Processes (Tina N. Grant and Frederick G. West). 5 Silver-Catalyzed Cycloisomerization Reactions (Philippe Belmont). 6 Silver-Catalyzed Nitrene Transfer Reactions (Zigang Li, David A. Capretto, and Chuan He). 7 Silver-Catalyzed Silylene Transfer (Tom G. Driver). 8 Silver Carbenoids (Carl J. Lovely). 9 Aldol and Related Processes (Masanori Kawasaki and Hisashi Yamamoto). 10 Coupling Reactions Promoted by Silver (Jean-Marc Weibel, Aurélien Blanc, and Patrick Pale). 11 Supramolecular Chemistry of Silver (Wei-Yin Sun, Zheng-Shuai Bai, and Jin-Quan Yu). 12 A Critical Comparison: Copper, Silver, and Gold (A. Stephen K. Hashmi). References. Index.
Foreword. Preface. Contributors. 1 Silver Alkyls, Alkenyls, Aryls, and Alkynyls in Organic Synthesis ( Rebecca H. Pouwer and Craig M. Williams). 2 Cycloaddition Reactions (Alex M. Szpilman and Erick M. Carreira). 3 Sigmatropic Rearrangements and Related Processes Promoted by Silver ( Jean-Marc Weibel, Aurélien Blanc, and Patrick Pale). 4 Silver(I)-Mediated Electrocyclic Processes (Tina N. Grant and Frederick G. West). 5 Silver-Catalyzed Cycloisomerization Reactions (Philippe Belmont). 6 Silver-Catalyzed Nitrene Transfer Reactions (Zigang Li, David A. Capretto, and Chuan He). 7 Silver-Catalyzed Silylene Transfer (Tom G. Driver). 8 Silver Carbenoids (Carl J. Lovely). 9 Aldol and Related Processes (Masanori Kawasaki and Hisashi Yamamoto). 10 Coupling Reactions Promoted by Silver (Jean-Marc Weibel, Aurélien Blanc, and Patrick Pale). 11 Supramolecular Chemistry of Silver (Wei-Yin Sun, Zheng-Shuai Bai, and Jin-Quan Yu). 12 A Critical Comparison: Copper, Silver, and Gold (A. Stephen K. Hashmi). References. Index.
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