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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. The spin transition is an example of transition between two electronic states in molecular chemistry. The ability of an electron to transit from a stable to another stable (or metastable) electronic state in a reversible and detectable fashion, makes these molecular systems appealing in the field of molecular electronics. When a transition metal ion of configuration dn, n = 4 to 7, is in octahedral surroundings, its ground state may be low spin (LS) or high spin (HS), depending to a first approximation on the magnitude of the energy gap between eg and t2g metal orbitals relative to the mean spin pairing energy P.