This well-known laboratory manual introduces students to modern synthetic and instrumental techniques currently used in inorganic chemistry. The new Third Edition has been updated to reflect the latest developments in inorganic chemistry - giving greater emphasis to applications related to biochemistry and materials science. But the book retains many distinguishing features of previous editions, such as closely associating synthesis and characterization methods and highlighting a particular technique with each experiment.
This well-known laboratory manual introduces students to modern synthetic and instrumental techniques currently used in inorganic chemistry. The new Third Edition has been updated to reflect the latest developments in inorganic chemistry - giving greater emphasis to applications related to biochemistry and materials science. But the book retains many distinguishing features of previous editions, such as closely associating synthesis and characterization methods and highlighting a particular technique with each experiment.
Gregory S. Girolami, Thomas Rauchfuss, Robert Angelici
Inhaltsangabe
Introduction Safety Laboratory Procedures Research Notebook Standard References Part I. Solid State Chemistry Experiment 1--High-Temperature Synthesis of the Superconductor YBa2Cu3O7Tube Furnace Preparation Superconductivity Iodometric Titrations Experiment 2--The Layered Solids VOPO4(H2O)2 and VO(HPO4)(H2O)0.5Powder X-Ray Diffraction Oxidation of Alcohols to Ketones Experiment 3--The Molecular Sieve Zeolite-XSol-gel Synthesis High Pressure Synthesis Ion Exchange in Microporous Solids Part II. Main Group Chemistry Experiment 4--The Borane-Amine Adduct BH3NH2C(CH3)3Lewis Acids and Bases Experiment 5--Buckminsterfullerene, C60, and Its ElectrochemistrySoxhlet Extraction Cyclic Voltammetry Experiment 6--Vacuum-Line Synthesis of GeH4Vacuum Line and Trap-to-Trap Purification Vapor Pressure and Molecular Weight Determination of a Volatile Compound Gas Phase IR Spectroscopy Experiment 7--Tin Chemistry: Coordination Complexes and Organometallic DerivativesNMR Spectroscopy Linkage Isomerism Experiment 8--Synthesis of (C6H5)2PCH2CH2P(C6H5)2 in Liquid Ammonia Synthesis in Liquid Ammonia Experiment 9--Electrolytic Synthesis of K2S2O8Electrolytic Preparation Part III. Coordination Chemistry Experiment 10--Ion Exchange Separation of Chromium Complexes Ion Exchange Chromatography Experiment 11--Metal-Metal Quadruple Bonds Molecular Orbital Theory Experiment 12--The Magnetic Susceptibility of Mn(acac)3Magnetism of Transition Metal Complexes The Gouy Method The Evans MethodsExperiment 13--Cobalt Ammines and their Ligand Substitution KineticsConductivity of Ionic Complexes Kinetics of Aquation of [Co(NH3)5Cl]2+ Experiment 14--Optical Resolution of Co(en)33+Separation of Diastereomers by Crystallization Optical Rotations Suction Filtration Experiment 15--Metal Dithiolenes and the Use of Quaternary Ammonium Salts Quaternary Ammonium Salts Part IV. Organometallic Chemistry Experiment 16--The Metal-Arene Complex [1,3,5-C6H3(CH3)3]Mo(CO)3IR Spectra of Metal Carbonyls Experiment 17--Organo-iron Chemistry: (C5H5)2Fe2(CO)4 and (C5H5)Fe(CO)2(CH3)Schlenk Line Synthesis Infrared Spectra of Solutions Experiment 18--The Metal Carbonyl Cluster Fe3(CO)12Mass Spectrometry Experiment 19--Microscale Synthesis of Vaska's Complex Microscale Synthesis Solid State IR Spectra Experiment 20--The Air-Sensitive Sandwich Complex Nickelocene Glove Bag Manipulations Sublimation Part V. Bioinorganic Chemistry Experiment 21--Cobaloximes: Models of Vitamin-B12 Coenzymes Enzyme Models Experiment 22--Amino Acid Complexes: Stability Constants of Ni(glycinate)n(2 - n)+Amino Acid ChemistrypH TitrationspKa and Successive Stability Constant Determination Experiment 23--Bioinorganic Coordination Chemistry: Copper (II) Tetraphenylporphyrinate Porphyrin Chemistry Thin-Layer Chromatography Column Chromatography Notes to the Instructor Appendices NMR and Mass Spectra Index
Introduction Safety Laboratory Procedures Research Notebook Standard References Part I. Solid State Chemistry Experiment 1--High-Temperature Synthesis of the Superconductor YBa2Cu3O7Tube Furnace Preparation Superconductivity Iodometric Titrations Experiment 2--The Layered Solids VOPO4(H2O)2 and VO(HPO4)(H2O)0.5Powder X-Ray Diffraction Oxidation of Alcohols to Ketones Experiment 3--The Molecular Sieve Zeolite-XSol-gel Synthesis High Pressure Synthesis Ion Exchange in Microporous Solids Part II. Main Group Chemistry Experiment 4--The Borane-Amine Adduct BH3NH2C(CH3)3Lewis Acids and Bases Experiment 5--Buckminsterfullerene, C60, and Its ElectrochemistrySoxhlet Extraction Cyclic Voltammetry Experiment 6--Vacuum-Line Synthesis of GeH4Vacuum Line and Trap-to-Trap Purification Vapor Pressure and Molecular Weight Determination of a Volatile Compound Gas Phase IR Spectroscopy Experiment 7--Tin Chemistry: Coordination Complexes and Organometallic DerivativesNMR Spectroscopy Linkage Isomerism Experiment 8--Synthesis of (C6H5)2PCH2CH2P(C6H5)2 in Liquid Ammonia Synthesis in Liquid Ammonia Experiment 9--Electrolytic Synthesis of K2S2O8Electrolytic Preparation Part III. Coordination Chemistry Experiment 10--Ion Exchange Separation of Chromium Complexes Ion Exchange Chromatography Experiment 11--Metal-Metal Quadruple Bonds Molecular Orbital Theory Experiment 12--The Magnetic Susceptibility of Mn(acac)3Magnetism of Transition Metal Complexes The Gouy Method The Evans MethodsExperiment 13--Cobalt Ammines and their Ligand Substitution KineticsConductivity of Ionic Complexes Kinetics of Aquation of [Co(NH3)5Cl]2+ Experiment 14--Optical Resolution of Co(en)33+Separation of Diastereomers by Crystallization Optical Rotations Suction Filtration Experiment 15--Metal Dithiolenes and the Use of Quaternary Ammonium Salts Quaternary Ammonium Salts Part IV. Organometallic Chemistry Experiment 16--The Metal-Arene Complex [1,3,5-C6H3(CH3)3]Mo(CO)3IR Spectra of Metal Carbonyls Experiment 17--Organo-iron Chemistry: (C5H5)2Fe2(CO)4 and (C5H5)Fe(CO)2(CH3)Schlenk Line Synthesis Infrared Spectra of Solutions Experiment 18--The Metal Carbonyl Cluster Fe3(CO)12Mass Spectrometry Experiment 19--Microscale Synthesis of Vaska's Complex Microscale Synthesis Solid State IR Spectra Experiment 20--The Air-Sensitive Sandwich Complex Nickelocene Glove Bag Manipulations Sublimation Part V. Bioinorganic Chemistry Experiment 21--Cobaloximes: Models of Vitamin-B12 Coenzymes Enzyme Models Experiment 22--Amino Acid Complexes: Stability Constants of Ni(glycinate)n(2 - n)+Amino Acid ChemistrypH TitrationspKa and Successive Stability Constant Determination Experiment 23--Bioinorganic Coordination Chemistry: Copper (II) Tetraphenylporphyrinate Porphyrin Chemistry Thin-Layer Chromatography Column Chromatography Notes to the Instructor Appendices NMR and Mass Spectra Index
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