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High Quality Content by WIKIPEDIA articles! Volume fractions i are useful alternatives to mole fractions xi when dealing with mixtures in which there is a large disparity between the sizes of the various kinds of molecules; e.g., polymer solutions. They provide a more appropriate way to express the relative amounts of the various components.Thermodynamic functions using volume fractions reduce to mole-fraction expressions for mixtures of rigid molecules of roughly equal size. For macromolecules, there is a question about whether they behave as flexible, random coils (see Flory-Huggins solution…mehr

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High Quality Content by WIKIPEDIA articles! Volume fractions i are useful alternatives to mole fractions xi when dealing with mixtures in which there is a large disparity between the sizes of the various kinds of molecules; e.g., polymer solutions. They provide a more appropriate way to express the relative amounts of the various components.Thermodynamic functions using volume fractions reduce to mole-fraction expressions for mixtures of rigid molecules of roughly equal size. For macromolecules, there is a question about whether they behave as flexible, random coils (see Flory-Huggins solution theory), or whether they have compact structures like globular proteins. In addition to entropic questions, there are others concerning energy.