After a brief introduction to some basic concepts, the perturbation theory approach follows the hierarchy of interactions starting with the largest. The other interactions of spin, and angular momentum of the outermost electrons with each other, the nucleus and external magnetic fields are treated in order of descending strength. A spectroscopic perspective is generally taken by relating the observations of atomic radiation emitted or absorbed to the internal energy levels involved. X-ray spectra are then discussed in relation to the energy levels of the innermost electrons. Finally, a brief description is given of some modern, laser-based, spectroscopic methods for the high-resolution study of the details of atomic structure.
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