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A practical and authoritative examination of the electrochemical energy conversion In Electrochemical Energy Conversion via Small Molecule Catalysis, a team of distinguished researchers delivers an up-to-date discussion of state-of-the-art techniques of electrochemical energy conversion conducted with small molecule catalysis. The authors cover the foundational concepts and theories relevant to the technique, electrochemical oxygen evolution reaction, electrochemical oxygen reduction reaction, and electrochemical carbon-nitrogen coupling reaction. Readers will find detailed explorations…mehr
A practical and authoritative examination of the electrochemical energy conversion
In Electrochemical Energy Conversion via Small Molecule Catalysis, a team of distinguished researchers delivers an up-to-date discussion of state-of-the-art techniques of electrochemical energy conversion conducted with small molecule catalysis. The authors cover the foundational concepts and theories relevant to the technique, electrochemical oxygen evolution reaction, electrochemical oxygen reduction reaction, and electrochemical carbon-nitrogen coupling reaction.
Readers will find detailed explorations of the characterization techniques and the computational approaches for catalysis evaluation and prediction. You'll also discover examinations of the mechanisms and development status of many widely employed energy conversion reactions.
The book includes:
A thorough introduction to constant-potential modeling in CO2 reduction
Comprehensive explorations of advanced in situ characterization techniques for direct observation of gas-involved electrochemical reactions
Practical discussions of dynamic structural evolution identification via x-ray absorption fine structure
Complete treatments of catalysts for electrocatalytic oxygen reduction reaction
Perfect for electrochemists, catalytic chemists, and materials scientists, Electrochemical Energy Conversion via Small Molecule Catalysis will also benefit chemical engineers, environmental chemists, and polymer chemists.
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Autorenporträt
Zhicheng Zhang, PhD, is currently a Professor of Tianjin University in China. He is the Associate Editor of SmartMat and an editorial board member of Nano Research, Chinese Chemical Letters, and Rare Metals. Yuanmiao Sun, PhD, is a Professor of Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences. His research is focused on the design of efficient functional materials via multi-dimensional computation modeling and calculation.
Inhaltsangabe
1 INTRODUCTION 1.1 Origins and Evolution of Small Molecule Catalysis for Electrochemical Energy Conversion 1.2 Current State of Small Molecule Catalysis in Electrochemical Energy Conversion 1.3 Challenges in Small Molecule Catalysis for Electrochemical Energy Conversion 1.4 Opportunities and Future Outlook
2 ELECTROCHEMICAL ENERGY CONVERSION TECHNIQUES 2.1. Introduction: The Future is Electrifying 2.2. Fuel Cells and Electrolyzers 2.3. Batteries and Supercapacitors 2.4. Summary
3 CONSTANT-POTENTIAL MODELING IN ELECTROCHEMICAL CO2 REDUCTION 3.1 Introduction 3.2 Principle of Constant-Potential Modeling 3.3 Constant-Potential Modeling of Electrochemical CO2RR 3.3 Conclusion and Outlook
4 ADVANCED IN SITU CHARACTERIZATION TECHNIQUES FOR DIRECT OBSERVATION OF GAS-INVOLVED ELECTROCHEMICAL REACTIONS 4.1 Introduction 4.2 In Situ Infrared Technique 4.3 Electrochemical Quartz Crystal Microbalance 4.4 X-Ray Powder Diffraction 4.5 In Situ Differential Electrochemical Mass Spectrometer 4.6 In Situ Raman Spectroscopy 4.7 In Situ Fluorescence Spectrum 4.8 X-Ray Photoelectron Spectrometer 4.9 Ultroviolet Photoelectron Spectrometer
5 DYNAMIC STRUCTURAL EVOLUTION IDENTIFICATION VIA X-RAY ABSORPTION FINE STRUCTURE 5.1 Introduction 5.2 Fundamentals of XAFS 5.3 XAFS Data Analysis and Interpretation 5.4 In-situ and Operando XAFS Techniques 5.5 Advanced XAFS Methods 5.6 Dynamic Structural Evolution in Catalysts 5.7 Application of XAFS in Electrochemical Energy Conversion 5.8 Conclusions and Outlook
6 ELECTROCHEMICAL HYDROGEN EVOLUTION REACTION 6.1 Introduction 6.2 Performance Evaluation Criteria and Methods 6.3 Advanced Electrocatalysts for HER 6.4 Summary and Perspective
7 ELECTROCHEMICAL OXYGEN EVOLUTION REACTION 7.1 Introduction 7.2 The state-of-the-art characterization techniques 7.3 OER mechanisms 7.4 The mechanism and development status of some typical energy conversion reactions 7.5 Catalysis evaluation and prediction 7.6 Conclusion
9 CATALYSTS FOR ELECTROCATALYTIC OXYGEN REDUCTION REACTION 9.1 Introduction 9.2 The ORR mechanism 9.3 ORR catalyst characterization techniques 9.4 The category of ORR catalyst 9.5 Pd-based metal catalysts 9.6 Non-platinum group metal catalysts 9.7 Metal-free catalysts 9.8 Single atom catalysts 9.9 Conclusion and Outlook
10 ELECTROCHEMICAL CONVERSION OF BIOMASS DERIVATIVES 10.1 Introduction 10.2 Fundamentals of electrooxidation of biomass derivatives 10.3 Cathodic reaction in biomass electrooxidation system 10.4. Challenges and Future Perspectives
11 ELECTROCHEMICAL CO2 REDUCTION AND CONVERSION 11.1 Introduction 11.2 Fundamentals of Electrochemical CO2 Reduction 11.3 Catalysts for Electrochemical CO2 Reduction 11.4 Mechanisms and Pathways of Electrochemical CO2 Reduction 11.5 Challenges and Opportunities 11.6 Case Studies and Applications 11.7 Future Perspectives 11.8 Conclusion
1 INTRODUCTION 1.1 Origins and Evolution of Small Molecule Catalysis for Electrochemical Energy Conversion 1.2 Current State of Small Molecule Catalysis in Electrochemical Energy Conversion 1.3 Challenges in Small Molecule Catalysis for Electrochemical Energy Conversion 1.4 Opportunities and Future Outlook
2 ELECTROCHEMICAL ENERGY CONVERSION TECHNIQUES 2.1. Introduction: The Future is Electrifying 2.2. Fuel Cells and Electrolyzers 2.3. Batteries and Supercapacitors 2.4. Summary
3 CONSTANT-POTENTIAL MODELING IN ELECTROCHEMICAL CO2 REDUCTION 3.1 Introduction 3.2 Principle of Constant-Potential Modeling 3.3 Constant-Potential Modeling of Electrochemical CO2RR 3.3 Conclusion and Outlook
4 ADVANCED IN SITU CHARACTERIZATION TECHNIQUES FOR DIRECT OBSERVATION OF GAS-INVOLVED ELECTROCHEMICAL REACTIONS 4.1 Introduction 4.2 In Situ Infrared Technique 4.3 Electrochemical Quartz Crystal Microbalance 4.4 X-Ray Powder Diffraction 4.5 In Situ Differential Electrochemical Mass Spectrometer 4.6 In Situ Raman Spectroscopy 4.7 In Situ Fluorescence Spectrum 4.8 X-Ray Photoelectron Spectrometer 4.9 Ultroviolet Photoelectron Spectrometer
5 DYNAMIC STRUCTURAL EVOLUTION IDENTIFICATION VIA X-RAY ABSORPTION FINE STRUCTURE 5.1 Introduction 5.2 Fundamentals of XAFS 5.3 XAFS Data Analysis and Interpretation 5.4 In-situ and Operando XAFS Techniques 5.5 Advanced XAFS Methods 5.6 Dynamic Structural Evolution in Catalysts 5.7 Application of XAFS in Electrochemical Energy Conversion 5.8 Conclusions and Outlook
6 ELECTROCHEMICAL HYDROGEN EVOLUTION REACTION 6.1 Introduction 6.2 Performance Evaluation Criteria and Methods 6.3 Advanced Electrocatalysts for HER 6.4 Summary and Perspective
7 ELECTROCHEMICAL OXYGEN EVOLUTION REACTION 7.1 Introduction 7.2 The state-of-the-art characterization techniques 7.3 OER mechanisms 7.4 The mechanism and development status of some typical energy conversion reactions 7.5 Catalysis evaluation and prediction 7.6 Conclusion
9 CATALYSTS FOR ELECTROCATALYTIC OXYGEN REDUCTION REACTION 9.1 Introduction 9.2 The ORR mechanism 9.3 ORR catalyst characterization techniques 9.4 The category of ORR catalyst 9.5 Pd-based metal catalysts 9.6 Non-platinum group metal catalysts 9.7 Metal-free catalysts 9.8 Single atom catalysts 9.9 Conclusion and Outlook
10 ELECTROCHEMICAL CONVERSION OF BIOMASS DERIVATIVES 10.1 Introduction 10.2 Fundamentals of electrooxidation of biomass derivatives 10.3 Cathodic reaction in biomass electrooxidation system 10.4. Challenges and Future Perspectives
11 ELECTROCHEMICAL CO2 REDUCTION AND CONVERSION 11.1 Introduction 11.2 Fundamentals of Electrochemical CO2 Reduction 11.3 Catalysts for Electrochemical CO2 Reduction 11.4 Mechanisms and Pathways of Electrochemical CO2 Reduction 11.5 Challenges and Opportunities 11.6 Case Studies and Applications 11.7 Future Perspectives 11.8 Conclusion
