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This book comprehensively covers iodine, its chemistry, and its role in functional materials, reagents, and compounds. * Provides an up-to-date, detailed overview of iodine chemistry with discussion on elemental aspects: characteristics, properties, iodides, and halogen bonding * Acts as a useful guide for readers to learn how to synthesize complex compounds using iodine reagents or intermediates * Describes traditional and modern processing techniques, such as starch, cupper, blowing out, and ion exchange resin methods * Includes seven detailed sections devoted to the applications of iodine:…mehr
This book comprehensively covers iodine, its chemistry, and its role in functional materials, reagents, and compounds. * Provides an up-to-date, detailed overview of iodine chemistry with discussion on elemental aspects: characteristics, properties, iodides, and halogen bonding * Acts as a useful guide for readers to learn how to synthesize complex compounds using iodine reagents or intermediates * Describes traditional and modern processing techniques, such as starch, cupper, blowing out, and ion exchange resin methods * Includes seven detailed sections devoted to the applications of iodine: Characteristics, Production, Synthesis, Biological Applications, Industrial Applications, Bioorganic Chemistry and Environmental Chemistry, and Radioisotopes * Features hot topics in the field, such as hypervalent iodine-mediated cross coupling reactions, agrochemicals, dye sensitized solar cells, and therapeutic agents
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Autorenporträt
Tatsuo Kaiho is the Director of Nihon Tennen Gas Co., Ltd. (Chiba, Japan), one of the most well-known iodine manufacturing companies in the world. The Director of the Society of Iodine Science, Dr. Kaiho developed novel iodine-containing materials and processes and presented independent research at many conferences, including the International Conference of Hypervalent Iodine Chemistry (2010) and the Symposium of Iodine Science (2011). Dr. Kaiho has received several awards, such as the Distinguished Chemist Award from Chiba Prefectural Government (2001) and the Society of Iodine Science Award (2012).
Inhaltsangabe
LIST OF CONTRIBUTORS ix
Preface xiii
1 Overview 1 Tatsuo Kaiho
Part I Characteristics, elemental of iodine 7
2 Physical Properties of Iodine 9 Tatsuo Kaiho
3 A nalytical Methods for Iodine and Iodides 15 Hirofumi Kanoh and Takehisa Konishi
4 Ion Chromatography 25 Anna Blazewicz
5 Inorganic Iodides 55 Tatsuo Kaiho
6 Organic Iodides 75 Tsugio Kitamura
7 H ypervalent Iodine 103 Toshifumi Dohi and Yasuyuki Kita
8 Iodine and Halogen Bonding 159 Giancarlo Terraneo, Giuseppe Resnati, and PierangeloMetrangolo
Part II Pro duction of iodine 195
9 H istory of Iodine 197 James L. Marshall and Virginia R. Marshall
10 Production Process in the Past 207 Tatsuo Kaiho
11 Iodine Production from Caliche 213 Armin Lauterbach
12 Iodine Production from Oilfield Brine 221 Stanley T. Krukowski
13 Iodine Production from Natural Gas Brine 231 Nobuyuki Kaneko and Tatsuo Kaiho
14 Recycling of Iodine 243 Tatsuo Kaiho
Part III Synthesis of iodine compounds 249
15 Iodinating Reagents 251 Haruhiko Taguchi
16 Oxidizing Agents 277 Toshifumi Dohi and Yasuyuki Kita
17 Reaction of Iodo Compounds 303 Toshifumi Dohi and Yasuyuki Kita
18 Metal Iodides-Mediated Reaction 329 Makoto Shimizu, Iwao Hachiya and Junji Inanaga
Part IV Biological Application of iodine 353
19 Iodinated X-Ray Contrast Agents 355 Werner Krause
20 Iodine as Disinfectant 375 Waldemar Gottardi
21 Synthetic Thyroid Hormone 411 Steven E. Rokita
22 Iodine Deficiency Disorders and Their Correction UsingIodized Salt and/or Iodine Supplements 421 Michael B. Zimmermann
