Nonnitrogenous Organocatalysis (eBook, PDF)

Redaktion: Harned, Andrew

• Format: PDF

Produktbeschreibung

Since the 1990s the synthetic community has shown a growing interest in the development of catalytic reactions that employ entirely organic catalysts - so-called 'organocatalysts'. With the current emphasis on green chemistry throughout the chemical industry, organocatalysis has become indispensible. In spite of this growth and recognition, there can be a misconception that organocatalysts are only based on nitrogen-containing functional groups (amines, ureas, and quaternary ammonium salts, for example), and are only useful for asymmetric reactions.

Nonnitrogenous Organocatalysis shows that the umbrella of organocatalysis covers other main group elements besides nitrogen, and the coverage is not just limited to asymmetric methods. Many of the catalysts and mechanisms discussed may not have a viable asymmetric variant or cannot be rendered asymmetric at all. This does not make them any less useful, as illustrated in this book.

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Produktdetails

• Verlag: Taylor & Francis eBooks
• Seitenzahl: 261
• Erscheinungstermin: 12. Dezember 2017
• Englisch
• ISBN-13: 9781498715058
• Artikelnr.: 50519517

Autorenporträt

Andrew Harned, PhD, is an assistant professor in the Department of Chemistry at the University of Minnesota, Minneapolis, Minnesota, USA

Inhaltsangabe

Oxidations with Ketone Catalysts. Chiral Brønsted Acid Catalysts Derived
from Phosphorous and Boron. Alcohols and Phenols as Hydrogen Bonding
Catalysts. Chiral and Achiral Organoiodine Catalysis. Halogen Bonding
Catalysis: An Emerging Paradigm in Organocatalysis. Organoselenium
Catalysis. Sulfide Catalysts. Utility of Phosphine Oxide Catalysts in
Synthesis. Utility of Phosphine Catalysts in Synthesis. N-Heterocyclic
Carbene Catalysis: Homoenolate and Enolate Reactivity. N-Heterocyclic
Carbene Catalysis: Acyl Anion and Acylcinyl Anion Equivalents.