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Science of Synthesis: Houben-Weyl Methods of Molecular Transformations is the entirely new edition of the acclaimed reference series Houben-Weyl, the standard synthetic chemistry resource since 1909. This new edition is published in English and will comprise 48 volumes published between the years 2000 and 2008. Science of Synthesis is a quality reference work developed by a highly esteemed editorial board to provide a comprehensive and critical selection of reliable organic and organometallic synthetic methods. This unique resource is designed to be the first point of reference when…mehr
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations is the entirely new edition of the acclaimed reference series Houben-Weyl, the standard synthetic chemistry resource since 1909. This new edition is published in English and will comprise 48 volumes published between the years 2000 and 2008.
Science of Synthesis is a quality reference work developed by a highly esteemed editorial board to provide a comprehensive and critical selection of reliable organic and organometallic synthetic methods. This unique resource is designed to be the first point of reference when searching for a synthesis strategy.
Contains the expertise of presently 400 leading chemists worldwide
Critically evaluates the preparative applicability and significance of the synthetic methods
Discusses relevant background information and provides detailed experimental procedures
For full information on the Science of Synthesis series, visit the Science of Synthesis Homepage
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Autorenporträt
Houben-Weyl
Inhaltsangabe
<p>35.1 Product Class 1: One Saturated Carbon—Chlorine Bond<br>35.1.1 Product Subclass 1: Chloroalkanes<br>35.1.1.1 Synthesis by Substitution of Hydrogen<br>35.1.1.2 Synthesis by Substitution of Metals<br>35.1.1.3 Synthesis by Substitution of Carbon Functionalities<br>35.1.1.4 Synthesis by Substitution of Other Halogens<br>35.1.1.5 Synthesis by Substitution of Oxygen Functionalities<br>35.1.1.6 Synthesis by Substitution of Sulfur, Selenium, or Tellurium Functionalities<br>35.1.1.7 Synthesis by Substitution of Nitrogen Functionalities<br>35.1.1.8 Synthesis by Addition to π-Type C—C Bonds<br>35.1.1.9 Synthesis from Other Chlorine Compounds<br>35.1.2 Product Subclass 2: Propargylic Chlorides<br>35.1.3 Product Subclass 3: Benzylic Chlorides<br>35.1.3.1 Synthesis by Substitution of Hydrogen<br>35.1.3.2 Synthesis by Substitution of Carbonyl Oxygen<br>35.1.3.3 Synthesis by Substitution of σ-Bonded Heteroatoms<br>35.1.4 Product Subclass 4: Allylic Chlorides<br>35.1.4.1 Synthesis by Substitution of Hydrogen α to a C=C Bond<br>35.1.4.2 Synthesis by Substitution of σ-Bonded Heteroatoms<br>35.1.5 Product Subclass 5: 1-Chloro-n-Heteroatom-Functionalized Alkanes (n ≥2) with Both Functions Formed Simultaneously<br>35.1.5.1 Synthesis by Addition across C=C Bonds<br>35.1.5.2 Synthesis by Addition across C—O Bonds<br>35.1.5.3 Synthesis by Addition across C—S Bonds<br>35.1.5.4 Synthesis by Addition across C—N Bonds<br>35.1.5.5 Synthesis by Addition across C—C Bonds<br>35.2 Product Class 2: One Saturated Carbon—Bromine Bond<br>35.2.1 Product Subclass 1: Bromoalkanes<br>35.2.1.1 Synthesis by Substitution of Hydrogen<br>35.2.1.2 Synthesis by Substitution of Metals<br>35.2.1.3 Substitution of Carbon Functionalities<br>35.2.1.4 Synthesis by Substitution of Other Halogens<br>35.2.1.5 Synthesis by Substitution of Oxygen Functionalities<br>35.2.1.6 Synthesis by Substitution of Sulfur, Selenium, or Tellurium Functionalities<br>35.2.1.7 Synthesis by Substitution of Nitrogen Functionalities<br>35.2.1.8 Synthesis by Addition to π-Type C—C Bonds<br>35.2.1.9 Synthesis from Other Bromo Compounds<br>35.2.2 Product Subclass 2: Propargylic Bromides<br>35.2.3 Product Subclass 3: Benzylic Bromides<br>35.2.3.1 Synthesis by Substitution of Hydrogen<br>35.2.3.2 Synthesis by Substitution of Carbonyl Oxygen<br>35.2.3.3 Synthesis by Substitution of σ-Bonded Heteroatoms<br>35.2.4 Product Subclass 4: Allylic Bromides<br>35.2.4.1 Synthesis by Substitution of Hydrogen α to a C=C Bond<br>35.2.4.2 Synthesis by Substitution of σ-Bonded Heteroatoms<br>35.2.5 Product Subclass 5: 1-Bromo-n-Heteroatom-Functionalized Alkanes (n ≥2) with Both Functions Formed Simultaneously<br>35.2.5.1 Synthesis by Addition across C=C Bonds<br>35.2.5.2 Synthesis by Addition across C—O Bonds<br>35.2.5.3 Synthesis by Addition across C—S Bonds<br>35.2.5.4 Synthesis by Addition across C—N Bonds<br>35.2.5.5 Synthesis by Addition across C—C Bonds<br>35.3 Product Class 3: One Saturated Carbon—Iodine Bond<br>35.3.1 Product Subclass 1: Iodoalkanes<br>35.3.1.1 Synthesis by Substitution of Hydrogen<br>35.3.1.2 Synthesis by Substitution of Metals<br>35.3.1.3 Synthesis by Substitution of Carbon Functionalities<br>35.3.1.4 Synthesis by Substitution of Other Halogens<br>35.3.1.5 Synthesis by Substitution of Oxygen Functionalities<br>35.3.1.6 Synthesis by Substitution of Sulfur, Selenium, or Tellurium Functionalities<br>35.3.1.7 Synthesis by Substitution of Nitrogen Functionalities<br>35.3.1.8 Synthesis by Addition to π-Type C—C Bonds<br>35.3.1.9 Synthesis from Other Iodo Compounds<br>35.3.2 Product Subclass 2: Propargylic Iodides<br>35.3.3 Product Subclass 3: Benzylic Iodides<br>35.3.3.1 Synthesis by Substitution of Carbonyl Oxygen<br>35.3.3.2 Substitution of σ-Bonded Heteroatoms<br>35.3.4 Product Subclass 4: Allylic Iodides<br>35.3.5 Product Subclass 5: 1-Iodo-n-Heteroatom-Functionalized Alkanes (n ≥2) with Both Functions Formed Simultaneously<br>35.3.5.1 Synthesis by Addition across C=C Bonds<br>35.3.5.2 Synthesis by Addition across C—O Bonds<br>35.3.5.3 Synthesis by Addition across C—S Bonds<br>35.3.5.4 Synthesis by Addition across C—N Bonds<br>35.3.5.5 Synthesis by Addition across C—C Bonds</p>
<p>35.1 Product Class 1: One Saturated Carbon—Chlorine Bond<br>35.1.1 Product Subclass 1: Chloroalkanes<br>35.1.1.1 Synthesis by Substitution of Hydrogen<br>35.1.1.2 Synthesis by Substitution of Metals<br>35.1.1.3 Synthesis by Substitution of Carbon Functionalities<br>35.1.1.4 Synthesis by Substitution of Other Halogens<br>35.1.1.5 Synthesis by Substitution of Oxygen Functionalities<br>35.1.1.6 Synthesis by Substitution of Sulfur, Selenium, or Tellurium Functionalities<br>35.1.1.7 Synthesis by Substitution of Nitrogen Functionalities<br>35.1.1.8 Synthesis by Addition to π-Type C—C Bonds<br>35.1.1.9 Synthesis from Other Chlorine Compounds<br>35.1.2 Product Subclass 2: Propargylic Chlorides<br>35.1.3 Product Subclass 3: Benzylic Chlorides<br>35.1.3.1 Synthesis by Substitution of Hydrogen<br>35.1.3.2 Synthesis by Substitution of Carbonyl Oxygen<br>35.1.3.3 Synthesis by Substitution of σ-Bonded Heteroatoms<br>35.1.4 Product Subclass 4: Allylic Chlorides<br>35.1.4.1 Synthesis by Substitution of Hydrogen α to a C=C Bond<br>35.1.4.2 Synthesis by Substitution of σ-Bonded Heteroatoms<br>35.1.5 Product Subclass 5: 1-Chloro-n-Heteroatom-Functionalized Alkanes (n ≥2) with Both Functions Formed Simultaneously<br>35.1.5.1 Synthesis by Addition across C=C Bonds<br>35.1.5.2 Synthesis by Addition across C—O Bonds<br>35.1.5.3 Synthesis by Addition across C—S Bonds<br>35.1.5.4 Synthesis by Addition across C—N Bonds<br>35.1.5.5 Synthesis by Addition across C—C Bonds<br>35.2 Product Class 2: One Saturated Carbon—Bromine Bond<br>35.2.1 Product Subclass 1: Bromoalkanes<br>35.2.1.1 Synthesis by Substitution of Hydrogen<br>35.2.1.2 Synthesis by Substitution of Metals<br>35.2.1.3 Substitution of Carbon Functionalities<br>35.2.1.4 Synthesis by Substitution of Other Halogens<br>35.2.1.5 Synthesis by Substitution of Oxygen Functionalities<br>35.2.1.6 Synthesis by Substitution of Sulfur, Selenium, or Tellurium Functionalities<br>35.2.1.7 Synthesis by Substitution of Nitrogen Functionalities<br>35.2.1.8 Synthesis by Addition to π-Type C—C Bonds<br>35.2.1.9 Synthesis from Other Bromo Compounds<br>35.2.2 Product Subclass 2: Propargylic Bromides<br>35.2.3 Product Subclass 3: Benzylic Bromides<br>35.2.3.1 Synthesis by Substitution of Hydrogen<br>35.2.3.2 Synthesis by Substitution of Carbonyl Oxygen<br>35.2.3.3 Synthesis by Substitution of σ-Bonded Heteroatoms<br>35.2.4 Product Subclass 4: Allylic Bromides<br>35.2.4.1 Synthesis by Substitution of Hydrogen α to a C=C Bond<br>35.2.4.2 Synthesis by Substitution of σ-Bonded Heteroatoms<br>35.2.5 Product Subclass 5: 1-Bromo-n-Heteroatom-Functionalized Alkanes (n ≥2) with Both Functions Formed Simultaneously<br>35.2.5.1 Synthesis by Addition across C=C Bonds<br>35.2.5.2 Synthesis by Addition across C—O Bonds<br>35.2.5.3 Synthesis by Addition across C—S Bonds<br>35.2.5.4 Synthesis by Addition across C—N Bonds<br>35.2.5.5 Synthesis by Addition across C—C Bonds<br>35.3 Product Class 3: One Saturated Carbon—Iodine Bond<br>35.3.1 Product Subclass 1: Iodoalkanes<br>35.3.1.1 Synthesis by Substitution of Hydrogen<br>35.3.1.2 Synthesis by Substitution of Metals<br>35.3.1.3 Synthesis by Substitution of Carbon Functionalities<br>35.3.1.4 Synthesis by Substitution of Other Halogens<br>35.3.1.5 Synthesis by Substitution of Oxygen Functionalities<br>35.3.1.6 Synthesis by Substitution of Sulfur, Selenium, or Tellurium Functionalities<br>35.3.1.7 Synthesis by Substitution of Nitrogen Functionalities<br>35.3.1.8 Synthesis by Addition to π-Type C—C Bonds<br>35.3.1.9 Synthesis from Other Iodo Compounds<br>35.3.2 Product Subclass 2: Propargylic Iodides<br>35.3.3 Product Subclass 3: Benzylic Iodides<br>35.3.3.1 Synthesis by Substitution of Carbonyl Oxygen<br>35.3.3.2 Substitution of σ-Bonded Heteroatoms<br>35.3.4 Product Subclass 4: Allylic Iodides<br>35.3.5 Product Subclass 5: 1-Iodo-n-Heteroatom-Functionalized Alkanes (n ≥2) with Both Functions Formed Simultaneously<br>35.3.5.1 Synthesis by Addition across C=C Bonds<br>35.3.5.2 Synthesis by Addition across C—O Bonds<br>35.3.5.3 Synthesis by Addition across C—S Bonds<br>35.3.5.4 Synthesis by Addition across C—N Bonds<br>35.3.5.5 Synthesis by Addition across C—C Bonds</p>
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